Distribution of Mg and Fe in cummingtonite-hornblende and cummingtonite-actinolite pairs from metamorphic assemblages     

Hanan J. Kisch  F. W. Warnaars 《Contributions to Mineralogy and Petrology》1969,24(3):245-267

The atomic fractions Mg/(Mg + Fe) and the Mg-Fe distribution coefficient $$K_{{\text{D}}{\text{.Mg - Fe}}}^{{\text{Ca - am - Cum}}} \left( { = \tfrac{{[{\text{Mg/Fe]}}_{{\text{Ca - am}}} }}{{{\text{[Mg/Fe]}}_{{\text{Cum}}} }}} \right)$$ are calculated for 31 metamorphic cummingtonite-hornblende pairs. Data on 21 pairs are taken from the litterature, and new electron microprobe analyses and structural formulae are presented of nine pairs from Tydal, Sör-Tröndelag, Norway, and of one pair from Cooma, N.S.W., Australia (cf. Kisch, 1969). The electron microprobe methods used are described, particularly the use of mineral standards, and the variation of the mass absorption in substitution series. The hornblendes from the Tydal pairs are markedly pargasitic in composition, and contain minor proportions of the cummingtonite “molecule”. The Mg-Fe distributions in the cummingtonite-hornblende pairs — as plotted on a [Mg/(Mg + Fe)]_Ca-am vs. [Mg/(Mg + Fe)]_Cum diagram (Fig. 3) — differ significantly from the Mg-Fe distribution curve for cummingtonite-actinolite pairs from Quebec (Mueller, 1961). Whereas the actinolites have markedly higher Mg/Fe ratios than the co-existing cummingtonites (K _D.Mg-Fe ^Ca-am-Cum ≈ 1.5–2.0), the cummingtonite-hornblende pairs diverge towards lower values from the distribution coefficient. In most of the metamorphic cummingtonite-hornblende pairs — including the nine pairs from Tydal — the Mg/Fe ratio of the hornblende is lower than in the co-existing cummingtonite, i.e K _D.Mg-Fe ^Ca-am-Cum <1. A relation appears to exist between the Mg-Fe distribution and the Al content of the calcic amphibole phase. This is believed to be due to the non-random distribution of Al^Y among the octahedral lattice sites: in hornblende Al^VI enters the M ₁+M₃ positions, in which Mg is preferred over Fe, rather than M ₂, in which Fe is preferred (Ghose, 1965). Since the cummingtonites remain Al-poor, the over-all Mg/Fe ratio in the hornblende is reduced relative to the co-existing cummingtonite as a result. The variations of the Mg-Fe distribution in the cummingtonite-hornblende pairs can also be related directly to the presence and composition of the plagioclase and other Al-rich phases in the metamorphic mineral assemblage. In any range of Mg/Fe ratios, the cummingtonite-hornblende pairs associated with oligoclase have lower distribution coefficients (0.61–0.81; 12 pairs) than those associated with calcic plagioclase or plagioclase-free assemblages (0.97 to 1.89; 6 pairs); the pairs associated with andesine have intermediate Mg-Fe distributions (0.74–1.15; 6 pairs).  相似文献   

Primordial helium isotope signature from Plio–Quaternary alkaline basalts in Yemen     

Yuji Orihashi  Keisuke Nagao  Ashraf Al-Jailani  Barry B. Hanan 《Island Arc》2001,10(2):145-157

Abstract Isotopic compositions of He, Ne and Ar were measured on Plio–Quaternary alkaline basalts of Marib–Sirwah and Shuqra volcanic fields in Yemen, south-western Arabian Peninsula. Very high ³He/⁴He isotope ratios were found in olivine phenocrysts of some Quaternary alkaline basalts in both volcanic fields, located on the margin of the dispersed Afar mantle plume, compared with the Afar–Ethiopian province in the center of the mantle plume. This suggests that the Afar mantle plume source may consist of common component (C or focal zone (FOZO)) with variable primordial ³He/⁴He ratio rather than high μ mantle (HIMU) component. The three component mixing C as the Afar mantle plume, depleted mantle (DM) as upper mantle and lithospheric mantle with a hybrid enriched mantle I–II (EM I–EM II) characteristics may be adequate to explain He–Sr–Nd–Pb isotope variation for the Afar–Arabian Cenozoic volcanics. The occurrence of high ³He/⁴He ratios in the Marib–Sirwah volcanic field appears to show that the primitive basaltic magma, derived from the margin of the dispersed trous-like Afar mantle plume during 15–0 Ma, was not by contamination of lithospheric and upper mantle materials in comparison with that from the center of the Afar mantle plume as a result of relatively low thermal anomaly.  相似文献   

Late Quaternary environmental and human events at En Gedi, reflected by the geology and archaeology of the Moringa Cave (Dead Sea area, Israel)     

Sorin Lisker  Roi Porat  Hanan Eshel  Amos Frumkin 《Quaternary Research》2007,68(2):203-212

The Moringa Cave within Pleistocene sediments in the En Gedi area of the Dead Sea Fault Escarpment contains a sequence of various Pleistocene lacustrine deposits associated with higher-than-today lake levels at the Dead Sea basin. In addition it contains Chalcolithic remains and 5th century BC burials attributed to the Persian period, cemented and covered by Late Holocene travertine flowstone. These deposits represent a chain of Late Pleistocene and Holocene interconnected environmental and human events, echoing broader scale regional and global climate events. A major shift between depositional environments is associated with the rapid fall of Lake Lisan level during the latest Pleistocene. This exposed the sediments, providing for cave formation processes sometime between the latest Pleistocene (ca. 15 ka) and the Middle Holocene (ca. 4500 BC), eventually leading to human use of the cave. The Chalcolithic use of the cave can be related to a relatively moist desert environment, probably related to a shift in the location of the northern boundary of the Saharo-Arabian desert belt. The travertine layer was U-Th dated 2.46 ± 0.10 to 2.10 ± 0.04 ka, in agreement with the archaeological finds from the Persian period. Together with the inner consistency of the dating results, this strongly supports the reliability of the radiometric ages. The 2.46-2.10 ka travertine deposition within the presently dry cave suggests a higher recharge of the Judean Desert aquifer, correlative to a rising Dead Sea towards the end of the 1st millennium BC. This suggests a relatively moist local and regional climate facilitating human habitation of the desert.  相似文献   

Major and trace element and Sr–Nd isotope signatures of lavas from the Central Lau Basin: Implications for the nature and influence of subduction components in the back-arc mantle     

Liyan Tian  Paterno R. Castillo  James W. Hawkins  David R. Hilton  Barry B. Hanan  Aaron J. Pietruszka 《Journal of Volcanology and Geothermal Research》2008

New major and trace element and Sr–Nd isotope data are presented for basaltic glasses from active spreading centers (Central Lau Spreading Center (CLSC), Relay Zone (RZ) and Eastern Lau Spreading Center (ELSC)) in the Central Lau Basin, SW Pacific. Basaltic lavas from the Central Lau Basin are mainly tholeiitic and are broadly similar in composition to mid-ocean ridge basalts (MORB). Their generally high ⁸⁷Sr/⁸⁶Sr ratios, combined with relatively low ¹⁴³Nd/¹⁴⁴Nd ratios are more akin to MORB from the Indian rather than Pacific Ocean. In detail, the CLSC, RZ and ELSC lavas are generally more enriched in large ion lithophile elements (Rb, Ba, Sr, and K) than average normal-MORB, which suggests that the mantle beneath the Central Lau Basin was modified by subducted slab-derived components. Fluid mobile/immobile trace element and Sr – Nd isotope ratios suggest that the subduction components were essentially transferred into the mantle via hydrous fluids derived from the subducted oceanic crust; contributions coming from the subducted sediments are minor. Compared to CLSC lavas, ELSC and RZ lavas show greater enrichment in fluid mobile elements and depletion in high field strength elements, especially Nb. Thus, with increasing distance away from the arc, the influence of subduction components in the mantle source of Lau Basin lavas diminishes. The amount of hydrous fluids also influences the degree of partial melting of the mantle beneath the Central Lau Basin, and hence the degree of melting also decreases with increasing distance from the arc.  相似文献   

Isotopic geochemistry of Hualalai shield-stage tholeiitic basalts from submarine North Kona region,Hawaii     

Seiko Yamasaki  Tomomi Kani  Barry B. Hanan  Takahiro Tagami 《Journal of Volcanology and Geothermal Research》2009

The geochemical data of Hualalai tholeiitic basalts allow extension of the temporal variations established at Mauna Loa back in time, and provide important information for the long-term temporal variation of the Hawaiian lavas. We report new Hf, Pb, Nd, and Sr isotope compositions for 32 Hualalai tholeiitic basalts collected from deep submarine portions of the North Kona region. The samples were collected from the lower section of the North Kona bench (dives K218 and K219), a submarine stratigraphic section at Hualalai volcano's northwest rift zone (dive S690), and an elongate ridge outboard of the central section of the bench (dive S692), during two JAMSTEC Hawaii cruises in 2001 and 2002. The Hualalai shield-stage tholeiitic basalts have magma source isotopic signatures similar to Mauna Loa. The new data shows temporal Pb and Sr isotope trends that correspond to the long-term temporal variations in Loa-trend lavas, and the Hualalai–Mauna Loa lavas seem to show inter-shield geochemical excursions. Variation in Pb and Sr isotopes at Hualalai appears to take place over a longer time scale than at Mauna Loa. The merged Hualalai–Mauna Loa isotopic trends support models where heterogeneous material in the plume conduit is distributed chaotically, with variable cross-sectional density and length scale.  相似文献   

Geographical information system approach for environmental management in coastal area (Hardelot-Plage,France)     

Fadi Chaaban  Hanan Darwishe  Barbara Louche  Yvonne Battiau-Queney  Eric Masson  Jamal El Khattabi  Erick Carlier 《Environmental Earth Sciences》2012,65(1):183-193

The use of geographic information system (GIS) minimizes the effort and improves the efficiency of numerical models. The GIS provides a platform for high capacity collection, management, manipulation, analysis, modeling and display of spatial data. The conceptual model is created using GIS objects including points, arcs and polygons so that it can accurately represent real world condition. According to the research problem, the geographical model is based on Hypergraph Based Data Structure method, and a conceptual data model has been created from which a physical data model was elaborated in ArcGIS9.3 platform. The groundwater modeling system (GMS) provides a powerful tool for hydrodynamics modeling and it is able to solve complex problems such as the groundwater flow and seawater intrusion. The sand-dune system of Hardelot-Plage (North of France) suffers from a lack of well-developed foredune. This problem is linked to the almost constant saturation of beach sand which is the potential source of dune nourishment. In the south of Hardelot, the coastline is slowly, but constantly retreating. To remedy this situation, a coupling between a GIS and GMS was adopted, in order to find the possible scenarios which could lower the piezometric surface in the concerned area and allow dune nourishment again. The GMS used supports the Modflow-2000 code. A direct approach to designing Modflow finite difference model is tedious and less intuitive, specifically for complex boundary and initial conditions. Therefore, a Modflow model can be developed either using a grid or conceptual model approach. The preparation of input data modeling is tedious and takes a long time. The model created in GMS was calibrated against the historical and observed water level data for 1995–2006. Then a hydrodispersive model (MT3d code in GMS) was launched for evaluating sea-water intrusion. The model was run to generate groundwater and salt concentration scenario during pumping tests.  相似文献